混炼方式对螺旋纳米碳纤维增强天然橡胶复合材料力学性能的影响

采用干法和湿法两种混炼工艺制备了螺旋纳米碳纤维(HCNFs)/炭黑(CB)/天然橡胶(NR)复合材料,通过扫描电镜、拉伸试验机和应变扫描仪分别对所制备复合材料的界面形貌、力学性能和Payne效应进行了测试分析,考察了混炼方式对复合材料宏观力学性能及Payne效应的影响。结果表明,与纯CB填料相比,在干湿两种混炼方式下,添加适量的HCNFs(1～6份)能提高HCNFs/CB/NR复合材料的300%定伸应力、扯断伸长率、拉伸强度和硬度。与干法混炼相比,湿法混炼能明显增强HCNFs/CB/NR复合材料的Payne效应,并提升在HCNFs高添加量(2～6份)条件下的拉伸强度和扯断伸长率,这主要源于湿法混炼能够有效改善HCNFs在橡胶基质中的分散性。     

表面形态对铝合金表面注射结合性能的影响

通过对铝合金表面进行阳极氧化和偶联剂处理，提出了一种注塑工艺直接成形铝合金聚酰胺复合构件的方法。利用激光共焦扫描显微镜和傅里叶红外(FTIR)光谱仪对经处理过的铝合金表面结构和成分进行了分析，结果表明：铝合金表面粗糙度和偶联剂固化时形成的Si-O-Al、C-N等化学键对界面结合力有重要影响。讨论了阳极氧化工艺参数和偶联剂固化条件对铝合金表面形貌、成分和注塑复合构件力学性能的影响规律，借助扫描电子显微镜(SEM)分析了复合构件拉伸剪切的破坏机理。     

A new composite of crystalline silicotitanate for sequestration of 137Cs and 90Sr from low-level aqueous waste solution

ABSTRACT

A new composite of crystalline silicotitanate (CST) has been synthesized for the sequestration of Cs and Sr from low-level liquid waste generated in the nuclear industry. The product characterization using X-RAY DEFRACTION (XRD) and Fourier-transform infrared spectroscopy (FTIR) confirmed the presence of CST crystals in the composite. Sorption studies carried out under various test conditions showed that the composite has high affinity for both Cs and Sr. Results of structural characterization of Cs and Sr-loaded CST indicated that the overall structural integrity remained intact after substitution of Na⁺ by Cs⁺ or Sr²⁺. The exceedingly good Cs and Sr sorption performance displayed by the CST composite will find applications in the treatment of nuclear waste.     

石墨烯改性涂层防护性能研究

为减少团聚，提高石墨烯在涂层中的分散性，研究采用纳米分散技术预先制备了石墨烯分散液，再将其分散至环氧树脂中获得石墨烯改性复合涂层。通过对石墨烯含量为 0、0.3%、0.6%的复合涂层进行盐水浸泡、盐雾、阴极剥离实验及电化学性能测试，证明石墨烯的加入显著增强了涂层的防护性能。石墨烯复合涂层在 3.5%盐水中浸泡 1 008 h后，涂层低频阻抗仍大于 106 Ω·cm²比未添加石墨烯的涂层提高了 3个数量级，且盐雾实验 6 000 h后涂层表面仍保持完好；含 0.6%石墨烯，的涂层耐蚀行为劣于石墨烯含量为 0.3%的涂层。     

改性碱式氯化镁晶须/丁苯橡胶复合材料制备与性能研究

以工业活性轻烧氧化镁粉和盐酸为原料,采用水溶液法制备了碱式氯化镁晶须,继而采用硅烷偶联剂对碱式氯化镁晶须进行改性,然后将其与丁苯橡胶混炼得到改性碱式氯化镁晶须/丁苯橡胶复合材料,研究了改性碱式氯化镁晶须对丁苯橡胶力学性能及热学性能的影响。结果表明：采用水溶液法制备得到的碱式氯化镁晶须结构为Mg₂（OH）₃Cl·4H₂O,呈微细纤维状,分布较均匀,长径比大于20;改性碱式氯化镁晶须的加入,可以改善丁苯橡胶的机械强度和阻燃性能。     

Modeling and surface texturing on surface roughness in machining LaPO4–Y2O3 composite

In this work, lanthanum phosphate with a 20% yttria (LaPO₄/Y₂O₃) composite prepared by an Aqueous Sol–Gel process is machined using an Abrasive Water Jet Machine (AWJM). The machinability of this composite is studied by varying the input parameters namely Jet Pressure (JP), Stand-Off Distance (SOD), and Traverse Speed (TS) on Surface finish. Garnet of 80 mesh size is used as an abrasive with a flow rate of 85?g/min. The microstructural characterization study reveals the presence of new element YPO₄. This element enhances the machinability and reduced porosity in the composite. Microscopy examinations on the machined surface reveals that partial overlapping at low JP, poor surface finish at high JP and SOD, forged deficiency at maximum SOD and TS. The minimum levels of all input parameters are influenced to obtain acceptable Ra. Atomic Force Microscopy (AFM) on the kerf surface shows micro wear track and peaks. The Multiple Regression Analysis (MRA) is developed for Ra to check the adequacy. From the Analysis of Variance (ANOVA), SOD has a significant effect on Ra with a contribution of 53%. The influence of JP and TS on Ra is found to be 31% and 15%, respectively.     

基于近似测地线的分层次自动铺带轨迹规划方法

自动铺带技术是一种增量制造技术，适用于制造翼面、壁板等大尺寸、小曲率复合材料构件，具有加工成本低、效率高等特点。轨迹规划是自动铺带技术的关键环节，它直接关系到复合材料构件的成型精度与质量。现有的自动铺带轨迹规划方法难以便捷兼顾调控铺放间隙与防止铺放褶皱，保证铺带产品的最终质量。有鉴于此，提出了一种基于近似测地线的分层次铺放轨迹规划方法。主要目标是合理利用预浸带允许变形能力，在防止铺放褶皱产生的前提下，保证相邻带料不产生覆盖，且间隙不超过2.5 mm。首先，研究了铺放间隙的产生与演化规律，给出了几种典型曲面上初始铺放间隙的优化方法。接下来，提出了近似测地线的数学模型与求解格式。然后，基于铺放褶皱的产生机制与铺放间隙的演化规律，确定了近似测地线的测地曲率大小与符号。最后，在双曲面模具以及自由曲面模具上验证了所提出方法的有效性。     

复合外加剂改性盐石膏的研究

盐石膏的主要成分为无水硫酸钙,其活性差、凝结硬化慢、强度低,需要添加活性剂来激发盐石膏的活性。通过复合外加剂对盐石膏加以改性,并通过XRD和SEM对其作用机理做了分析。结果表明,单掺脱硫石膏和建筑石膏均能缩短盐石膏的凝结时间,建筑石膏的效果较好,但掺量不宜过高。复掺建筑石膏和缓凝剂时,两者比例要控制得当,适宜的建筑石膏和缓凝剂掺量分别为50%和0.10%~0.12%（质量分数）。分析可知,大掺量建筑石膏会增加盐石膏硬化体中二水相和针棒状晶体的含量;缓凝剂掺量的增加,会降低盐石膏硬化体中二水相的含量,棱形晶体增多,从而降低了盐石膏的强度。     

Fabrication and Characterization of Highly Oriented Composite Nanofibers with Excellent Mechanical Strength and Thermal Stability

Here, highly‐oriented poly(m‐phenylene isophthalamide)/polyacrylonitrile multi‐walled carbon nanotube (PMIA/PAN‐MWCNT) composite nanofiber membranes with excellent mechanical strength and thermal stability are successfully produced using electrospinning. It is demonstrated that the cooperation of multi‐walled carbon nanotubes (MWCNT) and high‐speed rotating collection is beneficial to the acquisition of highly oriented fibers and effectively improves the mechanical strength of the membrane along the orientation direction. Specifically, the tensile stress of poly(m‐phenylene isophthalamide)/polyacrylonitrile (PMIA/PAN) membrane is enhanced significantly from 10.6 to 20.7 MPa, benefiting from the highly oriented alignment of the fibers as well as the reinforcing effect of MWCNTs on the fibers. Furthermore, the stressing process of single fiber and fiber aggregates is carefully simulated, and the influence of MWCNTs on the mechanical properties of PMIA/PAN‐MWCNT membranes is analyzed comprehensively, providing a meaningful auxiliary means for the study of mechanical properties. In addition, the composite nanofiber membrane has the advantages of both PMIA and PAN, possessing high temperature resistance, flame‐retardancy, and chemical stability, for an ideal high‐temperature material. In short, the as‐prepared PMIA/PAN‐MWCNT composite membrane with excellent comprehensive property emerges a promising application in many fields, especially in high‐tech.     

碳纤维复合材料修复带缺陷储气井的应力分析及试验研究

针对天然气储气井井管外壁腐蚀现状,采用有限元计算方法,分析不同外壁腐蚀类型、不同腐蚀缺陷尺寸下储气井井管的应力分布、承载极限及疲劳性能;加工带缺陷储气井井管试件,选择碳纤维复合材料湿缠绕法补强修复;对修复后的井管试件进行有限元应力分析,并进行爆破试验和疲劳试验,以充分验证补强方法的有效性;储气井井管的理论分析和性能试验证明,碳纤维复合材料湿缠绕法补强可以有效地修复带外壁缺陷的储气井井管,有效、快捷地解决在役天然气储气井井管外壁腐蚀问题。